Title: | Ba6(MN4)N2–x (M = MoVI/TaV), a Subvalent Nitridometalate with Perovskite-like Crystal Structure |
Authors: | Wörsching, Matthias P.B. Fricke, Sarah Kristin Minár, Jan Niklaus, Robin Hoch, Constantin |
Citation: | WÖRSCHING, M. P., FRICKE, S. K., MINÁR, J., NIKLAUS, R., HOCH, C. Ba6(MN4)N2–x (M = MoVI/TaV), a Subvalent Nitridometalate with Perovskite-like Crystal Structure. Zeitschrift fur anorganische und allgemeine Chemie, 2019, roč. 645, č. 3, s. 278-283. ISSN 0044-2313. |
Issue Date: | 2019 |
Publisher: | Wiley |
Document type: | článek article |
URI: | 2-s2.0-85056359893 http://hdl.handle.net/11025/39560 |
ISSN: | 0044-2313 |
Keywords in different language: | Nitridometalates;Barium;Crystal structure;Subvalent compounds;Perovskite |
Abstract in different language: | The subvalent nitridometalate Ba-6[(Mo1-xTax)N-4]N-0.86 was prepared from mixtures of Mo powder with Ba, Na, and Ba2N at 600 degrees C in Ta ampoules. It crystallizes in space group Cmcm with a = 11.672(3), b = 10.177(2) and c = 10.8729(19) angstrom. Its crystal structure exhibits an orthorhombically distorted Perovskite topology with [Ba6N] building units forming the ReO3-type lattice via common vertices, and the nitridometalate anions occupying half of the available distorted cuboctahedral interstices. [MN4] anions show statistically mixed occupancy of M by Mo-VI and Ta-V. They show no notable deviation from nitridometalate anions in known ionic nitridomolybdates and -tantalates, and the metrics of the [Ba6N] octahedra correspond to those found in similar subvalent compounds. The nitrogen atom position centering the [Ba6N] octahedra is underoccupied. Band structure calculations corroborate the subvalent character of the compound and the two individual anionic structural building units. |
Rights: | Plný text není přístupný. © Wiley |
Appears in Collections: | Články / Articles (RAM) OBD |
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